I've had a trawl, and couldn't see that this had been done, so I thought I'd give it a go.
In order
5)Papa Lazarou - League of Gentlemen
4)Anthony Hancock - Hancock/Hancock's Half Hour
3)Edmund Blackadder - Blackadder
2)Ari Gould - Entourage
1)Basil Fawlty - Fawlty Towers
Mentions for Jack Donaghie (30 rock), Martin Ellingham (Doc Martin), Jim Royle (Royle Family), Marty Craine (Frasier), Kramer (Seinfeld), Gareth & David (The Office)...